Anti-freezing, Conductive Self-healing Organohydrogels with Stable Strain-Sensitivity at Subzero Temperatures

作者：Rong, Qinfeng; Lei, Wenwei; Chen, Lie; Yin, Yongai; Zhou, Jiajia; Liu, Mingjie^*

来源：Angewandte Chemie - International Edition, 2017, 56(45): 14159-14163.

DOI：10.1002/anie.201708614

• anti-freezing
• conductive organohydrogel
• hydrogels
• self-healing
• strain-sensitive

Conductive hydrogels are a class of stretchable conductive materials that are important for various applications. However, water-based conductive hydrogels inevitably lose elasticity and conductivity at subzero temperatures, which severely limits their applications at low temperatures. Herein we report anti-freezing conductive organohydrogels by using an H2O/ethylene glycol binary solvent as dispersion medium. Owing to the freezing tolerance of the binary solvent, our organohydrogels exhibit stable flexibility and strain-sensitivity in the temperature range from -55.0 to 44.6 degrees C. Meanwhile, the solvent molecules could form hydrogen bonds with polyvinyl alcohol (PVA) chains and induce the crystallization of PVA, greatly improving the mechanical strength of the organohydrogels. Furthermore, the non-covalent crosslinks endow the conductive organohydrogels with intriguing remoldability and self-healing capability, which are important for practical applications.

• 出版日期2017-11-6
• 单位北京航空航天大学