摘要

Copper complexes were directly prepared by electrochemical dissolution of copper in a cell without separating the cathode and anode spaces. The products were characterized by FT-IR and Raman spectra. The influence of temperature and conductive additives on product yield was also investigated. The experiments show that controlling temperature under 30 similar to 40 degreesC and selecting R4NBr as conductive additives improved product yield. The data also show that direct electrochemical preparation of copper complexes had high current efficiency and electrolysis yield. These copper complexes have high purity and can be directly used as precursor of nanometer oxides.