A chiral porous 3D metal-organic framework with an unprecedented 4-connected network topology

作者：Wu CD; Lin WB^*

来源：Chemical Communications, 2005, (29): 3673-3675.

DOI：10.1039/b505916j

A novel homochiral 3D metal-organic framework [CdL2(H2O)(2)][ClO4](2)center dot 2DMF center dot 3EtOH center dot 5/3H(2)O, 1, (L = (R)- 6,6';-dichloro- 2,2';-diethoxy-1,1';-binaphthyl-4,4';-bipyridine) exhibits an unprecedented 4-connected network topology owing to the cis- configuration of the Cd coordination and possesses permanent porosity as demonstrated by TGA, XRPD, and CO2 adsorption isotherm studies.

• 出版日期2005