A novel vic-dioxime ligand and its Ni(II), Cu(II) and Co(II) complexes containing calix[4]pyrrole moiety: synthesis, characterization and redox properties

作者：Taner Bilge^*; Deveci Pervin; Ozcan Emine; Solak Ali Osman

来源：Journal of Inclusion Phenomena and Macrocyclic Chemistry, 2012, 74(1-4): 391-396.

DOI：10.1007/s10847-012-0131-y

• Oxime
• vic-Dioxime
• Transition metal complex
• Calix[4]pyrrole
• Cyclic voltammetry

A new calix[4]pyrrole functionalized vic-dioxime, 3-(4-methyl-9,9,14,14,19,19-hexaethylcalix[4]pyrrole)benzoaminoglyoxime (LH2) was synthesized from anti-chloroglyoxime and 3-aminophenyl-calix[4]pyrrole at room temperature. The mononuclear complexes {nickel(II), copper(II) and cobalt(II)} of this vic-dioxime ligand were prepared and their structures were confirmed by elemental analysis, IR and UV-Vis spectrophotometry, magnetic susceptibility; the MS, H-1 and C-13 NMR spectra of the LH2 ligand and its Ni(II) complex were also recorded. The experimental results indicated that the ligand:metal ratio was 2:1 in the cases of Ni(II), Cu(II) and Co(II) complexes as is with most vic-dioximes. Electrochemical properties of the ligand, and its complexes were investigated in DMSO solution by cyclic voltammetry at 200 mV s(-1) scan rate.

• 出版日期2012-12