Asymmetric Synthesis of (+)-trans-Aerangis Lactone

作者:Kim Aejin; Sharma Satyasheel; Kwak Jong Hwan; Kim In Su*
来源:Bulletin of the Korean Chemical Society, 2013, 34(1): 75-78.
DOI:10.5012/bkcs.2013.34.1.75

摘要

Asymmetric synthesis of (+)-trans-aerangis lactone was achieved from commercially available 1-hexanol or 1-hexanal in four steps via iridium-catalyzed diastereoselective and enantioselective carbonyl crotylation from the alcohol or aldehyde oxidation level, and ruthenium-catalyzed olefin metathesis.

  • 出版日期2013-1-20