Application of dimensional analysis and similarity theory for simulation of electrode kinetics described by the Marcus-Hush-Chidsey formalism

作者：Protsenko V S^*; Danilov F I

来源：Journal of Electroanalytical Chemistry, 2012, 669: 50-54.

DOI：10.1016/j.jelechem.2012.01.028

• Similarity theory
• Dimensional analysis
• Charge transfer
• Electrochemical reaction
• Marcus-Hush-Chidsey model

Similarity theory and dimensional analysis were shown to be applicable for a kinetic analysis of an electrochemical reaction described by the Marcus-Hush-Chidsey (MHC) formalism. The corresponding dimensionless quantities (similarity criteria) were derived and approximating interrelations between them were analyzed. A convenient expression was obtained which connected the values of electrochemical rate constant, electrode polarization and reorganization energy in dimensionless complex coordinates.

• 出版日期2012-3-15
• 单位北京化工大学