Disilaferracycle Dicarbonyl Complex Containing Weakly Coordinated eta(2)-(H-Si) Ligands: Application to C-H Functionalization of Indoles and Arenes

作者：Sunada Yusuke^*; Soejima Hiroe; Nagashima Hideo

来源：Organometallics, 2014, 33(21): 5936-5939.

DOI：10.1021/om500794f

Well-defined iron complex-mediated catalytic C-3-selective silylation of indole derivatives and stoichiometric CH bond functionalization of arenes were achieved using an iron dicarbonyl complex containing the disilaferracycle moiety [o-(SiMe2)(2)C6H4]Fe(CO())2[o-{eta(2)-(H-SiMe2)(2)}C6H4] (1). Facile liberation of the eta(2)-(H-Si) groups in 1 was the key to effective promotion of these reactions.

• 出版日期2014-11-10