Unexpected One-Pot Synthesis of Diindolotriazatruxene: A Planar Electron-Rich Scaffold Toward Highly π-Extended PAHs

作者：Li, Xiangchun; Wang, Chunyu; Xue, Yibo; Meng, Cheng; Lai, Wen-Yong^*; Huang, Wei

来源：Asian Journal of Organic Chemistry, 2017, 6(12): 1749-1754.

DOI：10.1002/ajoc.201700498

• diindolotriazatruxene
• hydrocarbons
• optoelectronic properties
• polycyclic aromatic hydrocarbons
• structure elucidation

A unique planar and highly -extended scaffold, 3,8,14,19-tetrabromo-diindolotriazatruxene (4Br-DIT), was synthesized via a facile one-pot strategy. The structure of 4Br-DIT was adequately verified by MALDI-TOF mass spectrometry, H-1 and (CNMR)-C-13, and single-crystal XRD analysis. A combination of thermal, optical, and electrochemical investigation confirmed the electron-rich characteristics of the resulting diindolotriazatruxene unit, showing promise as a building block to construct highly -extended polycyclic aromatic hydrocarbons (PAHs).

• 出版日期2017-12
• 单位西北工业大学; 南京邮电大学