Degradation of Acid Orange II at neutral pH using Fe-2(MoO4)(3) as a heterogeneous Fenton-like catalyst

作者：Tian, S H; Tu, Y T; Chen, D S; Chen, X; Xiong, Y^*

来源：Chemical Engineering Journal, 2011, 169(1-3): 31-37.

DOI：10.1016/j.cej.2011.02.045

• Iron molybdate
• Solid acid
• Heterogeneous Fenton-like
• H2O2
• Acid Orange II

Iron molybdate, Fe-2(MoO4)(3), has been successfully prepared by a simple wet chemical process. Degradation of Acid Orange II (AOII) was studied in detail using Fe-2(MoO4)(3) as a heterogeneous Fenton-like catalyst. The results show that this new catalyst is highly effective for the degradation of AOII at neutral pH. For 100 mgl(-1) of the initial concentration with an initial pH of 6.7, the degradation efficiency of AOII reaches 94.1% within 60 min. Moreover, the catalytic activity is slightly affected by the solution pH in a wide range of 3.0-9.0. This indicates that the use of Fe-2(MoO4)(3) overcomes the low efficiency of Fenton-like reaction at neutral and even alkaline pH. Fe-2(MoO4)(3) exhibits low iron leaching, good structural stability and no loss of performance after five recycle times. A mechanism proposed herein suggests that the high catalytic activity can be attributed to the formation of an acidic microenvironment near the surface of the solid acid Fe-2(MoO4)(3) particles where catalysis occurs, as well as the synergistic effect of Fe3+ and MoO42-.

• 出版日期2011-5-1
• 单位中山大学