科研之友
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摘要
A gold-catalyzed 1,7-addition-cyclization-elimination cascade sequence performed on a range of alkynyl-substituted donor-acceptor-type cyclopropanes provides facile entry to highly functionalized exo-alkylidenecyclopentenes under very mild conditions. Isolation of the relevant allyl ether intermediate helped shed light on the reaction's mechanistic course.
- 出版日期2015-5-1
- 单位北京大学深圳研究生院
