Hydrothermal assembly and structural characterization of an unprecedented one-dimensional chain constructed from nickel diphosphopentamolybdate clusters

作者：Bo Q B^*; Sun Z X; Sun G X; Zhang Z W; Chen C L; Li Y X

来源：Journal of Coordination Chemistry, 2007, 60(3): 275-283.

DOI：10.1080/00958970600763607

• nickel
• phosphomolybdate
• hybrid compound
• hydrothermal synthesis
• crystal structure

A novel molybdenum phosphate complex, [Ni(1)(en)(2)(PO4)(2)Mo5O15][Ni(2)(en)(2-)(H2O)(2)] center dot H(2)en center dot 3H(2)O (1), has been synthesized under hydrothermal conditions. The complex was characterized by elemental analysis, FT-IR, DTA/TG and single crystal X-ray diffraction. The compound is orthorhombic, space group P2(1)2(1)2(1), with a = 12.580(3), b = 17.676(4), c = 17.969(4) angstrom, V = 3995.5(15) angstrom(3), Z = 4, and was refined to R-1 = 0.0301, wR(2) = 0.0715. It possesses an unprecedented one-dimensional chain structure constructed from molybdenum phosphate clusters and nickel complex fragments.

• 出版日期2007
• 单位暨南大学