Au-24(SAdm)(16) Nanomolecules: X-ray Crystal Structure, Theoretical Analysis, Adaptability of Adamantane Ligands to Form Au-23(SAdm)(16) and Au-25(SAdm)(16), and Its Relation to Au-25(SR)(18)

作者：Crasto David; Barcaro Giovanni; Stener Mauro; Sementa Luca; Fortunelli Alessandro^*; Dass Amala

来源：Journal of the American Chemical Society, 2014, 136(42): 14933-14940.

DOI：10.1021/ja507738e

Here we present the crystal structure, experimental and theoretical characterization of a Au-24(SAdm)(16) nanomolecule. The composition was verified by X-ray crystallography and mass spectrometry, and its optical and electronic properties were investigated via experiments and first-principles calculations. Most importantly, the focus of this work is to demonstrate how the use of bulky thiolate ligands, such as adamantanethiol, versus the commonly studied phenylethanethiolate ligands leads to a great structural flexibility, where the metal core changes its shape from five-fold to crystalline-like motifs and can adapt to the formation of Au24+/-1(SAdm)(16), namely, Au-23(SAdm)(16), Au-24(SAdm)(16), and Au-25(SAdm)(16). The basis for the construction of a thermodynamic phase diagram of Au nanomolecules in terms of ligands and solvent features is also outlined.

• 出版日期2014-10-22