A new class of polymeric complexes having Pt-Ag interactions Crystal structure of vertical bar{[(PPh3)(C6F5)Pt(mu-Cl)](2)Ag}(mu-Cl)(2)Ag(MeOH)vertical bar(n)

作者：Ara Irene; Aranaz Javier; Fornies Juan^*

来源：Journal of Fluorine Chemistry, 2010, 131(11): 1103-1107.

DOI：10.1016/j.jfluchem.2010.04.008

• Platinum
• Silver
• Polymer
• Metal-metal bond
• Pentafluorophenyl ligand

The reaction of (NBu4)[trans-PtCl2(C6F5)L] (L = PPh3 AsPh3) with AgClO4 (1 1) molar ratio in a CH2Cl2/MeOH mixture leads to the polymeric complexes [PtAgCl2(C6F5)L] (L = PPh3 1 AsPh3 2) The structure of complex vertical bar{[(PPh3)(C6F5)pt(mu-Cl)](2)Ag}(mu-Cl)(2)Ag(MeOH)vertical bar(n) (1 MeOH) has been

• 出版日期2010-11