Size-Controlled Synthesis of LiFePO4/C Composites as Cathode Materials for Lithium Ion Batteries

作者：Liu, Jiali^*; Wang, Zhangzhi; Zhang, Guohua; Liu, Yun; Yu, Aishui

来源：International Journal of Electrochemical Science, 2013, 8(2): 2378-2387.

DOI：10.1016/s1452-3981(23)14316-1

• Nano-microstructured micro-spherical
• spray-drying method
• lithium iron phosphate
• size-controlled synthesis
• electrochemical performance

Nano-micro-structured spherical LiFePO4/C composite is synthesized via a ball-milling-assisted spray-drying method. SEM characterization demonstrates that the primary and secondary particle sizes are on the order of several hundred nanometers and approximately fifteen microns. The primary particles are successfully controlled through homogenous milling with a narrow particle size distribution. Herein, LiFePO4/C composites with a primary particle (i.e., 200 nm and 400 nm in diameter) are prepared. The relationship between electrochemical performance and particle size is evaluated using both half- and full-cell tests. The results demonstrate that the 200 nm diameter sample has a better rate capability and low-temperature performance, whereas the 400 nm sample is better at cycling.

• 出版日期2013-2
• 单位复旦大学