An efficient and selective hydroarylation of styrenes with electron-rich arenes, catalyzed by bismuth(III) chloride and affording Markovnikov adducts

作者：Sun Hong Bin; Li Biao; Hua Ruimao^*; Yin Yingwu

来源：European Journal of Organic Chemistry, 2006, 2006(18): 4231-4236.

DOI：10.1002/ejoc.200600390

• arenes
• bismuth trichloride
• dimerization
• hydroarylation
• Markovnikov adduct

In the presence of BiCl3, the hydroarylation of styrenes with electron-rich arenes afforded Markovnikov adducts selectively in good to high yields. Under arene-free conditions, the intermolecular hydroarylation of a-substituted styrenes and subsequent intramolecular hydroarylation produced the cyclic dimers of a-substituted styrenes in good yields.

• 出版日期2006-9-11
• 单位清华大学