A Polar and Chiral Indium Telluride Featuring Supertetrahedral T2 Clusters and Nonlinear Optical Second Harmonic Generation

作者：Zhang Qichun; Chung In; Jang Joon I; Ketterson John B; Kanatzidis Mercouri G^*

来源：Chemistry of Materials, 2009, 21(1): 12-14.

DOI：10.1021/cm8027516

The "KIn(2)" Zintl phase activates tellurium under solvothermal conditions and yields the compound {[In(en)(3)][In(5)Te(9)(en)(2)] center dot 0.5en}(n) (en = ethylenediamine). The material has both a polar and chiral layered framework and exhibits type 1 phase-matchable strong second harmonic generation (SHG) response.

• 出版日期2009-1-13
• 单位西北大学