科研之友
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摘要
Cu-catalyzed click reaction of highly isotactic poly(propargyl methacrylate) with organic azides with a weakly coordinating monoamine was found to proceed to form blocky segments from H-1 NMR observation of monomer-sequence sensitive peak-splittings in the partially modified polymer, while the reaction with a highly coordinative triamine proceeded in a random fashion along the polymer chain.
- 出版日期2013
