A Neutral Gallium(I) N-Heterocyclic Carbene Analogue: Synthesis, Characterization and Theoretical Analysis

作者：Choong Sam L; Woodul William D; Stasch Andreas; Schenk Christian; Jones Cameron^*

来源：Australian Journal of Chemistry, 2011, 64(8): 1173-1176.

DOI：10.1071/CH11193

The six-membered N-heterocyclic gallium(I) compound [:Ga((But)Nacnac)] ((But)Nacnac(-)=[{N(Dip)C(Bu(t))}(2)CH](-), Dip = 2,6-diisopropylphenyl) has been synthesized, crystallographically characterized, and its electronic properties analyzed using density functional theory. For purposes of comparison, the isoelectronic cationic germanium(II) complex, [:Ge((But)Nacnac)][Al{OC(CF(3))(3)}(4)], has been prepared and structurally authenticated.

• 出版日期2011