A novel inorganic-organic tetragonal prism supramolecular compound [Fe(NCS)(6)][(Hbpy)(H(2)bpy)(bpy)]: crystal structure and non-linear optical properties

作者：Wei YL; Zhu Y; Song YL; Hou HW^*; Fan YT

来源：Inorganic Chemistry Communications, 2002, 5(2): 166-170.

DOI：10.1016/S1387-7003(02)00323-4

• supramolecular compound
• hydrogen bonds
• large dimensions
• third-order non-linear optical behavior

Inorganic-organic supramolecular compound [Fe(NCS)(6)][(Hbpy)(H(2)bpy)(bpy)] exhibits three-dimensional solid state structure constituted by hydrogen bonds N...H-N and S...H-C. [Fe(NCS)(6)](3-) groups form tetragonal prisms with the dimensions of 10.3 x 10.8 Angstrom(2), the bpy units occupy these prisms. The compound in DMF solution has very strong third-order non-linear optical behavior with refractive index n(2) of -2.95 x 10(-17) m(2) w(-1) and third-order non-linear optical susceptibility chi((3)) of 1.06 x 10(-10) esu.

• 出版日期2002-2
• 单位郑州大学; 哈尔滨工业大学