Macropolyhedral boron-containing cluster chemistry. Synthesis of the nineteen vertex monocarbaborane [9-((BuNH2)-Bu-ter)-(anti)-9-CB18H20] by direct carbon-atom Aufbau

作者：Jelinek Tomas; Cisarova Ivana; Stibr Bohumil; Kennedy John D^*

来源：Dalton Transactions, 2007, (42): 4766-4768.

DOI：10.1039/b714631k

[9-((BuNH2)-Bu-ter)-(anti)-9-CB18H20], in 36% yield from anti-B18H22, sodium naphthalene and (BuNC)-Bu-ter, constitutes the first example of a clean cluster carbon-addition Aufbau to form a macropolyhedral carbaborane.

• 出版日期2007