Adsorption Properties of N-2, CH4, and CO2 on Sulfur-Doped Microporous Carbons

作者：Su, Wei; Yao, Lan; Ran, Meng; Sun, Yan^*; Liu, Jia; Wang, Xiaojing^*

来源：Journal of Chemical and Engineering Data, 2018, 63(8): 2914-2920.

DOI：10.1021/acs.jced.8b00227

• POROUS CARBONS
• ACTIVATED CARBON
• HYDROGEN STORAGE
• NITROGEN
• PHOSPHORUS
• SEPARATION
• CAPTURE
• GAS

A series of sulfur-doped microporous carbon materials were prepared by directly using potassium hydroxide as the activating agent. The specific surface area and pore volume of the sample CKS-5 (activated at 800 degrees C for 180 min according to an alkali/carbon ratio of 4:1) reached 2088 m(2)/g and 1.240 cm(3)/g, respectively. The adsorption isotherms of N-2, CH4, and CO2 on five samples were determined by a volumetric method to obtain insight into the relationship between adsorption performance and porosity. CSK-5 with a developed pore structure exhibited a higher adsorption amount of CO2 and CH4 at high pressure. For the selectivity, the CS sample presented the highest selectivity for CO2/CH4, of which the selectivity of separation reached as high as 5.86. The highest selectivity of separation of CH4/N-2 (3.644) was present on CSK-7.

• 出版日期2018-8
• 单位天津大学; 南阳理工学院