MPEC-IMI as an effective green inhibitor to protect Q235 steel in 0.5M HCl medium

作者：Song, Li; Zhou, Yuming^*; Sheng, Xiaoli^*; Yao, Qingzhao; Xi, Xiaoyong

来源：Research on Chemical Intermediates, 2018, 44(10): 5833-5855.

DOI：10.1007/s11164-018-3459-0

• Green corrosion inhibitor
• Acid corrosion medium
• Polyethylene glycol monomethyl ether
• Quantum chemical calculations
• Molecular dynamics simulations

Imidazole (IMI)-based polyethylene glycol monomethyl ether (MPEC-IMI) as a novel green corrosion inhibitor was synthesized to protect the Q235 steel in 0.5M HCl corrosive medium at 318K. The inhibition performance of MPEC-IMI was investigated by weight loss measurement, the electrochemical method (Tafel and EIS) and surface analysis (SEM and EDX). The results reveal that the MPEC-IMI shows enhanced anticorrosion performance for carbon steel, which is attributed to the formation of the adsorptive protection film on the surface, and the type of adsorption basically obeys the Langmuir monolayer adsorption. Furthermore, when the concentration of MPEC-IMI is 300mgL(-1), the corrosion inhibition efficiency can reach up to 92.00%. In support of further study of the corrosion inhibition behavior by virtue of quantum chemical calculation and molecular dynamics simulations, the results show that the MPEC-IMI molecule has high reactivity and strong interaction on the iron surface.

• 出版日期2018-10
• 单位东南大学