A new hydrogen-bonding linked 3-D polyoxomolybdate

作者：Cui Jian^*; Gourigari Mahesh Babu

来源：Inorganic Chemistry Communications, 2016, 70: 14-17.

DOI：10.1016/j.inoche.2016.05.014

• Coordination polymers
• Crystal structure
• Polyoxomolybdate
• M4O13
• Hydrothermal reactions

The reactions under hydrothermal reaction conditions resulted in a hydrogen-bonding linked polyoxomolybdate [(NH4)(2)M4O13](n) 1 with three-dimensional (3-D) polymeric structure. The compound 1 is composed of three distinct (MoO6) and one (MoO5) mixed polyhedral connected by edge-sharing within the asymmetric unit displaying a covalent bonding four-step ladder network, and the ladder units linked via corner-sharing between asymmetric units showing an extended covalent bonding 2-D layer structure, and the 2-D networks are further linked by multiple hydrogen bonds to result in a 3-D polyoxomolybdate.

• 出版日期2016-8