An interdigitated 3D framework with 5-connected BN topology

作者：Wang, Cun-Kuan; Zhou, Yan; Xu, Lan-Ping; Han, Lei^*

来源：Inorganic Chemistry Communications, 2011, 14(7): 1174-1177.

DOI：10.1016/j.inoche.2011.04.019

• Coordination polymer
• Interdigitated framework
• BN topology
• 4,4 '-(hexafluoroisopropylidene)bis(benzoic acid)

A flexible coordination polymer 1 with interdigitated structure has been synthesized from 4,4'-(hexafluoroisopropylidene)bis(benzoic acid) ligand and Cd(2+) salt, whose 3D interdigitated framework displays novel 5-connected BN topology involving both covalent and strong hydrogen bonds. The luminescent properties of 1 are discussed.

• 出版日期2011-7
• 单位宁波大学