A new family of clusters containing a silver-centered tetracapped [Ag@Ag-4((3)-P)(4)] tetrahedron, inscribed within a N-12 icosahedron

作者：Artem'ev Alexander V^*; Bagryanskaya Irina Yu; Doronina Evgeniya P; Tolstoy Peter M; Gushchin Artem L; Rakhmanova Mariana I; Ivanov Alexander Yu; Suturina Anastasiya O

来源：Dalton Transactions, 2017, 46(37): 12425-12429.

DOI：10.1039/c7dt02597a

An unprecedented silver-centered P-tetracapped [Ag@Ag-4(mu(3)- P)(4)] tetrahedron inscribed within a N-12 icosahedral cage has been discovered in the novel family of luminescent clusters. The latter are easily self- assembled by reacting AgI salts with tris(2-pyridyl) phosphine (Py3P).

• 出版日期2017-10-7