{Tc(NO)(Cp)(PPh3)}(+) - a novel technetium(I) core

作者：Ackermann J; Hagenbach A; Abram U^*

来源：Chemical communications, 2016, 52(67): 10285-10288.

DOI：10.1039/c6cc05811f

Reactions between [TcI(NO)X-2(PPh3)(2)(CH3CN)] complexes (X = Cl, Br) and KCp form the pseudotetrahedral organotechnetium compounds [TcI(NO)(Cp)(PPh3)X]. The halide ligands can readily be replaced by other halides or organometallic ligands giving access to a novel family of technetium(I) compounds with the robust {Tc(NO)(Cp)(PPh3)}(+) core.

• 出版日期2016