Gold Nanoclusters as a Catalyst for Intramolecular Addition of Primary Amines to Unactivated Alkenes under Aerobic Conditions

作者：Kitahara Hiroaki; Sakurai Hidehiro^*

来源：Chemistry Letters, 2010, 39(1): 46-48.

DOI：10.1246/cl.2010.46

Gold nanoclusters stabilized by the poly(N-vinyl-2-pyrrolidone) hydrophilic polymer (Au:PVP) catalyzed the intramolecular cycloaddition of primary amines to unactivated alkenes in the presence of formic acid derivatives. The reaction proceeded under neutral to slightly acidic conditions in air.

• 出版日期2010-1-5