Apparent critical phenomena in the superionic phase transition of Cu2-xSe

作者：Kang Stephen Dongmin; Danilkin Sergey A; Aydemir Umut; Avdeev Maxim; Studer Andrew; Snyder G Jeffrey^*

来源：New Journal of Physics, 2016, 18(1): 013024.

DOI：10.1088/1367-2630/18/1/013024

• phase transition
• superioinic conductors
• thermoelectrics
• thermopower

The superionic phase transition of Cu2-xSe accompanies drastic changes in transport properties. The Seebeck coefficient increases sharply while the electrical conductivity and thermal diffusivity drops. Such behavior has previously been attributed to critical phenomena under the assumption of a continuous phase transition. However, applying Landau's criteria suggests that the transition should be first order. Using the phase diagram that is consistent with a first order transition, we show that the observed transport properties and heat capacity curves can be accounted for and modeled with good agreement. The apparent critical phenomena is shown to be a result of compositional degree-of-freedom. Understanding of the phase transition allows to explain the enhancement in the thermoelectric figure-of-merit that is accompanied with the transition.

• 出版日期2016-1-11
• 单位西北大学