A new triterpenoid saponin from Gymnema sylvestre

作者:Zhang, Man-Qi; Liu, Yue; Xie, Sheng-Xu; Xu, Tun-Hai*; Liu, Tong-Hua; Xu, Ya-Juan; Xu, Dong-Ming
来源:Journal of Asian Natural Products Research, 2012, 14(12): 1186-1190.
DOI:10.1080/10286020.2012.726517

摘要

Besides four known compounds, a new triterpenoid saponin was isolated from the stems of Gymnema sylvestre. The structure of the new triterpenoid saponin was established as 3 beta,16 beta,22 alpha-trihydroxy-olean-12-ene 3-O-beta-D-xylopyranosyl-(1 --> 6)-beta-D-glucopyranosyl-(1 --> 6)-beta-D-glucopyranoside (1) on the basis of 1D and 2D NMR techniques, including COSY, HMBC, HMQC, and NOESY correlations. Four known compounds 2, 3, 4, and 5 were identified on the basis of spectroscopic data.