A Parametric Analysis of the Basic Models of the Mechanisms of the Simplest Catalytic Reactions

作者:Bykov V I*; Tsybenova S B
来源:Russian Journal of Physical Chemistry, 2009, 83(4): 609-617.
DOI:10.1134/S0036024409040165

摘要

A series of the simplest thermokinetic models, in which the kinetic subsystem corresponds to traditional catalytic mechanisms, such as the Eley-Rideal mono- and bimolecular mechanisms and the Langmuir Hinshelwood mechanism, and autocatalytic mechanisms characterized by multiplicity of stationary states and autooscillations in the kinetic region, were considered. The method of continuation along a parameter was used for studying these basic models of thermokinetics. The parametric analysis performed allowed us to identify parameter regions characterized by critical effects (multiplicity of stationary states and autooscillations).