Anion-templated syntheses of octanuclear silver clusters from a silver dithiophosphate chain

作者：Liu, C. W.^*; Chang, How-Wei; Fang, Ching-Shiang; Sarkar, Bijay; Wang, Ju-Chun

来源：Chemical communications, 2010, 46(25): 4571-4573.

DOI：10.1039/b923388a

• X-RAY-STRUCTURE
• AG-S BONDS
• CRYSTAL-STRUCTURES
• COMPLEXES
• LIGANDS
• POLYMERS
• ALUMINA
• SALTS

Extended chain polymers [Ag(5){S(2)P(OEt)(2)}(4)(PF(6))](n), (1) could be converted to clusters of the type, [Ag(8)(X){S(2)P(OEt)(2)}(6)](PF(6)) [X = F (2); Cl (3); H (4)], by the addition of appropriate anions, of which [Ag(8)(H){S(2)P(OEt)(2)}(6)](+) showed a unique tetracapped-tetrahedral Ag8 core and contained Ag-mu-H-Ag linkages.

• 出版日期2010
• 单位苏州大学; 东华大学