A Review on Functionalized Ionic Liquids-based on Benzimidazolium Cation: Solvents for Synthesis and Catalysis

作者：Narayan Muskawar Prashant; Kumar Sythana Suresh; Arunrao Aswar Sachin; Karthikeyan Parasuraman; Rambhau Bhagat Pundlik^*

来源：Research Journal of Chemistry and Environment, 2011, 15(4): 92-103.

• Functionalized ionic liquids
• benzimidazolium cation
• solvents
• metal-mediated catalyst
• solar cell
• organic reactions

Functionalized ionic liquids (ILs) based on Benzimidazolium cation. as environmental friendly solvent and catalyst, high activity and selectivity and easily recovered materials were used to replace traditional volatile organic solvents which generally suffered from. disadvantages such as waste products, corrosion and environmental problems. Benzimidazole based ILS offered a new possibility for developing environmentally friendly basic catalyst with transition metal (Ag, Pd). They are flexible, nonvolatile, noncorrosive and immiscible with many organic solvents. This review presents an overview of. the preparation, extraction and applications in various reactions like Alkylation, Esterification, Acetalization, Benzoin reaction and Metal mediated catalyst in Suzuki, Suzuki Miyaura, Heak cross coupling and reduction, also in Anion Sensor, Solar Cell, Proton Conduction, Malaria Parasite and Biodiesel.

• 出版日期2011-12