An Eco-Friendly and Efficient Synthesis of Benzoylformic Acid and Methyl Benzoylformate from Styrene

作者：Dai, Zhihong; Peng, Xinhua^*; Dong, Xiongzi; Shi, Chunjie; Rong, Yuan

来源：Asian Journal of Chemistry, 2012, 24(11): 4979-4985.

• Styrene
• HBr/H2O2
• Benzoylformic acid
• Methyl benzoylformate
• TiO2/SO42-

The HBr/H2O2 system was found to be highly efficient and green catalytic system for the selective oxidation of styrene to benzoylformic acid in excellent yields under water as solvent. The process of etherification is simple, highly efficient and inexpensive by using TiO2/SO42- as catalyst.

• 出版日期2012-11
• 单位合肥工业大学