A novel organometallic macrocycle based on half-sandwich ruthenium motif

作者：Li, Xiu-Xiu; He, Qing-Ya; Wu, Fanghui; Yuan, Guozan; Yu, Wei-Bin^*

来源：Inorganica Chimica Acta, 2017, 454: 54-57.

DOI：10.1016/j.ica.2016.03.001

• Half-sandwich ruthenium
• Macrocycle
• Cyclic voltammetry
• Characterization
• Electronic properties
• Organic linker

The rational design and construction of a novel trinuclear macrocycle based on half-sandwich ruthenium was herein elaborated in detail, and consequently, fully characterized by 1D NMR, IR, EA and single crystal X-ray analysis, revealing its specific molecular structure which was a classic three-member ruthenium ring bridged by an organic linker [(E)-2-(2-(pyridin-4-yl)vinyl)quinolin-8-ol (HL)]. To further examine its photo and electronic properties, the mothed of UV-Vis and CV was carried out at ambient temperature, revealing it has a good application for catalyzing water oxidation under alkaline conditions.

• 出版日期2017-1-1
• 单位安徽工业大学