Ce2O2S anchored on graphitized carbon with tunable architectures as a new promising anode for Li-ion batteries

作者：Cheng, Juhong; Zhu, Jinliang; Wei, Xiaolin; Shen, Pei Kang^*

来源：Journal of Materials Chemistry A, 2015, 3(18): 10026-10030.

DOI：10.1039/c5ta00307e

Flower-like and dicranopteris-like Ce2O2S/carbon composites have been originally prepared by the heat treatment of S-containing ion-exchange resin and cerium acetate. The structure and morphology of the Ce2O2S/carbon are investigated by XRD, SEM, TEM and STEM. The flower-like Ce2O2S is self-assembled by porous single crystalline Ce2O2S sheets which are well anchored on carbon. The dicranopteris-like Ce2O2S/carbon is also comprised of single crystalline 'Ce2O2S leaves' surrounded by a carbon layer. The electrochemical performances of flower-like and dicranopteris-like Ce2O2S/carbon are studied by CV, galvanostatic discharge-charge tests and electrochemical impedance spectroscopy (EIS) measurements. The results show that the Ce2O2S/carbon has stable specific capacity up to 627 mA h g(-1) after 180 cycles at a constant current density of 50 mA g(-1) between 0.01 and 3 V. This performance can make it a choice as a potential anode material for Li-ion batteries.

• 出版日期2015
• 单位中山大学; 湘潭大学