New fluorescent sensor for antimony and transition metal cations based on rhodamine amide-arm homotrioxacalix[3]arene

作者:Wu, Chong; Zhang, Wen-Juan; Zeng, Xi*; Mu, Lan; Xue, Sai-Feng; Tao, Zhu; Yamato, Takehiko
来源:Journal of Inclusion Phenomena and Macrocyclic Chemistry, 2010, 66(1-2): 125-131.
DOI:10.1007/s10847-009-9665-z

摘要

A new fluorescent sensor 1 based on the rhodamine amide-armed homotrioxacalix[3]arene was synthesized, and its sensing behavior toward metal ions was investigated by UV-vis and fluorescence spectroscopies. Upon the addition of metal cations (Sb3+, Fe3+, Ni2+), a significant fluorescent enhancement in the range of 500-600 nm and colorimetric change was observed.