Cooperative catalysis by polymetallic copper-zinc complexes in the efficient oxidation of alcohols under solvent free condition

作者：Borthakur Rosrnita; Asthana Mrityunjaya; Kumar Arvind; Lal Ram A^*

来源：Inorganic Chemistry Communications, 2014, 46: 198-201.

DOI：10.1016/j.inoche.2014.05.018

• Cooperative catalysis
• Polymetallic complexes
• Oxidation
• Alcohols
• Carbonyl compounds

The oxidation of alcohols to corresponding aldehydes and ketones has been achieved using polymetallic complexes as catalyst with hydrogen peroxide as the terminal oxidant under a solvent free condition. These polymetallic complexes linked to a single ligand system exhibited remarkable cooperative effect in the oxidation process. This ecologically friendly procedure releases water as the only by-product.

• 出版日期2014-8