A New Cd(II) Coordination Polymer with a Rare tfz-d Topology Constructed by Asymmetrically Tricarboxylate and Imidazole-Containing Ligand: Synthesis, Crystal structure and Luminescent Property

作者：Yao Peng^*

来源：Journal of Inorganic and Organometallic Polymers and Materials, 2014, 24(3): 568-572.

DOI：10.1007/s10904-013-0006-8

• Crystal structure
• Cd(II)
• Luminescent property

A new coordination polymer [Cd(Hbtc)(bib)(0.5)] (n) (1) (H(3)btc = biphenyl-3,4',5-tricarboxylate and bib = 1,4-bis(imidazol-1-yl)benzene) has been obtained under hydrothermal conditions. The structure of complex 1 has been determined by single-crystal X-ray diffraction analysis and further characterized by elemental analysis and IR spectrum. The complex 1 shows a (3,8)-connected twofold interpenetrated three-dimensional (3D) tfz-d topology with the point symbol (4(3))(2) (4(6)center dot 6(18)center dot 8(4)). The photoluminescence behavior of complex 1 was also discussed in paper.

• 出版日期2014-5
• 单位新乡学院