Non-hydrothermal Synthesis of a Complex {[Zn(phen)(2)](2)(gamma-Mo8O26)} Constructed from [gamma-Mo8O26](4-) Anions

作者：Hao Zhaomin; Luo Weihong; Xu Xiuhong; Luo Fang^*

来源：Zeitschrift fur Naturforschung Section B-A Journal of Chemical Sciences, 2009, 64(4): 395-398.

DOI：10.1515/znb-2009-0406

• Non-hydrothermal Synthesis
• Inorganic-Organic Hybrid
• Octamolybdate

An octamolybdate-supported complex, {[Zn(Phen)(2)](2)(gamma-Mo8O26)} (phen = 1,10-phenanthroline) (1). has been obtained and characterized by IR spectroscopy, TGA analysis and single crystal X-ray diffraction. Crystal data: C48H40O26N8Mo8Zn2, monoclinic, P2(1)/n, a = 12.986(5), b = 16.704(5) c = 13.996(5) angstrom, beta = 106.551(5)degrees, V = 2910.2(18) angstrom(3), Z =2. The structure of compound 1 consists of a gamma-octamolybdate cluster covalently attached to two [Zn(phen)2](2 ) complexes. The complexes are tightly packed via C-H center dot center dot center dot O contacts between phen and [gamma-Mo8O26](4-) anions.

• 出版日期2009-4
• 单位东北师范大学; 吉林大学