科研之友
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摘要
The zero temperature adsorption isotherm of He-4 in a rigid cylindrical pore with alkali metal walls is computed within finite-range density functional theory, with the radius of the tube as a parameter. It is shown that starting from narrow pores and increasing the radius, the adsorbed helium first becomes bound in a quasi-onedimensional phase, and finally condenses into a quasi-twodimensional configuration by going through an almost filling situation. The results are in agreement with recent calculations for carbon nanotubes based on thermodynamical approaches.
- 出版日期2011-3
