A Copper-Carboxylate Layer-Framework with Pseudo-Kagome Net

作者:Wang, Xiao-Feng*; Zhang, Xiu-Lian; Zhou, Xin; Li, Jun; Kuang, Yun-Fei; Chen, Ji-Hao
来源:Zeitschrift fur Anorganische und Allgemeine Chemie, 2012, 638(9): 1365-1369.
DOI:10.1002/zaac.201200131

摘要

A two dimensional coordination polymer with pseudo-Kagome net [Cu3(btc)2(NH3)8(H2O)] was prepared from Cu(NO3)2.3H2O and 1, 3, 5-benzenetricarboxylic acid (btc) in ammonia aqua solution and was structurally characterized by X-ray diffraction. The magnetic susceptibility measurements, measured from 2 to 300 K, revealed a weak anti-ferromagnetic interaction between the CuII ions via the btc ligands.