A novel photosensitive ternary complex consisting of phenol-formaldehyde resin, sodium dodecyl sulfate, and diazo resin

作者：Zhang YJ; Cao WX^*

来源：Journal of Polymer Science Part A: Polymer Chemistry , 2000, 38(14): 2566-2571.

DOI：10.1002/1099-0518(20000715)38:14<2566::AID-POLA70>3.0.CO;2-U

• polyelectrolyte complexes
• diazoresin
• photosensitive material
• presensitized plates

A novel photosensitive ternary complex formed from phenol-formaldehyde resin (PR), sodium dodecyl sulfate (SDS), and diazo resin (DR) was developed. In the presence of SDS, PR remains soluble in water when its solution is neutralized. The PR-SDS-DR ternary complex forms when DR is added to the PR-SDS solution. The ternary complex dissolves in polar solvents such as dimethylformamide and is sensitive toward UV light or heating. It was confirmed that the ionic bond of -SO4 +N-2-between SDS and DR converts to a covalent bond after the decomposition of the N-1(2)- group under UV irradiation or heating. As a result, the solubility of PR-SDS-DR changes dramatically; that is, after treatment with UV light or heating, PR-SDS-DR becomes insoluble in polar solvents.

• 出版日期2000-7-15
• 单位北京大学