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摘要
A general thermolysis reaction for the transformation of Group 1 TMP compounds (LiTMP, NaTMP, KTMP) to 1-aza-allylic TTHP derivatives is reported. TMEDA accelerates the reaction and produces the crystalline complexes [(TMEDA) LiTTHP] and [(TMEDA.NaTTHP)(2)]. Methane elimination during the transformational process was confirmed via TVA coupled to MS.
- 出版日期2014
