Multiscale distribution of oxygen puddles in 1/8 doped YBa2Cu3O6.67

作者：Ricci Alessandro; Poccia Nicola; Campi Gaetano; Coneri Francesco; Caporale Alessandra Stella; Innocenti Davide; Burghammer Manfred; v Zimmermann Martin; Bianconi Antonio^*

来源：Scientific Reports, 2013, 3(1): 2383.

DOI：10.1038/srep02383

Despite intensive research a physical explanation of high T-c superconductors remains elusive. One reason for this is that these materials have generally a very complex structure making useless theoretical models for a homogeneous system. Little is known on the control of the critical temperature by the space disposition of defects because of lack of suitable experimental probes. X-ray diffraction and neutron scattering experiments used to investigate y oxygen dopants in YBa2Cu3O6+y lack of spatial resolution. Here we report the spatial imaging of dopants distribution inhomogeneity in YBa2Cu3O6.67 using scanning nano X-ray diffraction. By changing the X-ray beam size from 1 micron to 300 nm of diameter, the lattice inhomogeneity increases. The ordered oxygen puddles size distribution vary between 6-8 nm using 1 x 1 mu m(2) beam, while it is between 5-12 nm with a fat tail using the 300 x 300 nm(2) beam. The increased inhomogeneity at the nanoscale points toward a network of superconducting puddles made of ordered oxygen interstitials.

• 出版日期2013-8-8