科研之友
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摘要
The oxidative finictionalization of the benzylic C-H bonds in tetrahydroisoquinolines and tetrahydro-beta-carboline derivatives was investigated. C-C bond forming reactions proceeded with a range of nudeophiles (nitroallkane, enol silyl ether, indole, allylstannane, and tetrabutylammonium cyanide) under metal-free conditions and an oxygen atmosphere. Acetic acid caused a significant acceleration effect.
- 出版日期2014-8-15
