A new 2D heterometallic Cu/Cd mixed-anion polymer with dicyanamide and thiocyanate bridges formed via the reaction of elemental copper, cadmium dicyanamide and ethylenediamine

作者：Nesterova OV; Petrusenko SR^*; Kokozay VN; Skelton BW; Linert W

来源：Inorganic Chemistry Communications, 2004, 7(3): 450-454.

DOI：10.1016/j.inoche.2004.01.004

• heterometallic complex
• dicyanamide
• thiocyanate
• elemental copper
• ethylenediamine
• crystal structure

The new heterometallic 2D polymer [Cu(en)(2)Cd(dca)(2)(SCN)(2)]n (en = ethylenediamine; dca = dicyanamide, N(CN)(2)(-)), the first example of a compound containing the unique mixed-anion Cd(dca)2(SCN, fragment, has been prepared from copper powder, cadmium dicyanamide, ammonium thiocyanate and ethylenediamine in methanol solution in air. The polymeric sheets of the compound comprise two different rings - 28-membered [CU2Cd4( mu(1,5)-dca)(2)( mu(1,3)-NCS)(4)] macrocycles in which two 12-membered [Cd-2(mu(1.5)-dca)(2)] rings form sections.

• 出版日期2004-3