Development of T2EHDGA Based Process for Actinide Partitioning. Part I: Batch Studies for Process Optimization

作者：Gujar R B; Ansari S A; Mohapatra P K; Manchanda V K^*

来源：Solvent Extraction and Ion Exchange, 2010, 28(3): 350-366.

DOI：10.1080/07366291003685383

• T2EHDGA
• diglycolamide
• actinide partitioning
• waste management

N,N,N',N'-tetra-2-ethylhexyl diglycolamide (T2EHDGA) has been used for the extraction of actinides, lanthanides, fission products, and structural elements from Pressurized Heavy Water Reactor High Level Waste (PHWR-HLW). In view of third-phase formation under loading conditions, iso-decanol, tri-n-butyl phosphate (TBP), and N,N-di-n-hexyl octanamide (DHOA) were evaluated as the phase modifiers along with T2EHDGA. The loading of lanthanides (e.g. Nd(III), used as surrogate for trivalent minor actinides, Am(III) and Cm(III) and rare earth elements) in the organic phase sharply increased with the addition of iso-decanol as compared to other modifiers (TBP and DHOA). A minimum concentration of phase modifiers needed to avoid third-phase formation for 0.1 M T2EHDGA was 5% iso-decanol, 20% TBP or 20% DHOA. The most promising system, viz. 0.1 M T2EHDGA and 5% (v/v) iso-decanol was evaluated as extractant for actinide partitioning. The distribution behavior of various metal ions, viz. Am, Pu, U, Eu, Sr, Pd, Cs, Tc, Fe, and Mo has been studied from nitric acid as well as from synthetic PHWR-HLW using the optimized organic phase. Extraction of Am (tracer) from synthetic PHWR-HLW suggested a quantitative recovery of minor actinides in four contacts, while stripping (with 0.01 M HNO(3)) was quantitative in two contacts at O/A = 1. The testing of the optimized extraction system in mixer-settlers with simulated HLW is in progress.

• 出版日期2010