A hierarchically core/shell-structured titanosilicate with multiple mesopore systems for highly efficient epoxidation of alkenes

作者:Li, Chen Geng; Lu, Yiqun; Wu, Haihong; Wu, Peng*; He, Mingyuan
来源:Chemical Communications, 2015, 51(80): 14905-14908.
DOI:10.1039/c5cc05278e

摘要

A hierarchical titanosilicate, with epitaxially grown MFI nanosheets on microsized TS-1 crystals, has been prepared through a desilication-recrystallization method using a diammonium surfactant as the secondary structure-directing agent (SDA). This core/shell material features multiple mesoporosities, significantly improved epoxidation activity as well as easy separation in synthesis and catalytic reactions.