All-cellulose films with excellent strength and toughness via a facile approach of dissolution-regeneration

作者：Cheng, Geng; Zhu, Puxin; Li, Jiali; Cheng, Fei; Lin, Yi; Zhou, Mi^*

来源：Journal of Applied Polymer Science, 2019, 136(2): 46925.

DOI：10.1002/app.46925

• NAOH/UREA AQUEOUS-SOLUTION
• RAPID DISSOLUTION
• SODIUM-HYDROXIDE
• COMPOSITE FILMS
• CLAY NANOPAPER
• SURFACE
• FIBERS
• MATRIX
• SPECTROSCOPY
• NANOFIBERS

This study describes a green method for preparing all-cellulose nanocomposites through a dissolution and regeneration process. Cotton linter pulp was dissolved in 7 wt % NaOH/12 wt % urea aqueous solution precooled to -12 degrees C. Self-assembly of cellulose molecules into nanostructured cellulose fiber is achieved by using water addition and controlling the temperature to regenerate cellulose. By changing the microenvironment of the cellulose solution, the morphology of the nanostructured cellulose fibers and the mechanical properties of the regenerated cellulose films can be tuned. Then, a series of regenerated cellulose films have been prepared and characterized from various aspects. Compared with other all-cellulose films in the literature, the regenerated all-cellulose nanocomposite films prepared in this work exhibited good optical transparency, thermal stability, and excellent tensile strength (up to 135 MPa) when the regeneration temperature was adjusted to 50 degrees C. This work provided a green and promising approach to prepare high-performance and environmentally friendly all-cellulose nanocomposites.

• 出版日期2019-1-10
• 单位四川大学