Unexpected fluorescence properties in an axially sigma-bonded ferrocenyl-containing porphyrin

作者:Solntsev Pavlo V; Sabin Jared R; Dammer Samantha J; Gerasimchuk Nikolay N; Nemykin Victor N*
来源:Chemical Communications, 2010, 46(35): 6581-6583.
DOI:10.1039/c0cc02171g

摘要

Molecular structure, redox, and unexpected fluorescence properties of a tetraphenylporphyrin tin(IV) complex axially sigma-bonded with two ferrocene substituents were investigated using UV-vis, MCD, electro- and spectroelectrochemical methods as well as DFT calculations and X-ray crystallography.

  • 出版日期2010